Quality Manufacturer Supply 83901-88-6 with Efficient Shipping, Buy High Grade 4-Cyanomethylbenzoic acid
- Molecular Formula:C11H11NO2
- Molecular Weight:189.214
- Melting Point:28 °C
- Boiling Point:325.971 °C at 760 mmHg
- Flash Point:153.252 °C
- PSA：50.09000
- Density:1.113 g/cm3
- LogP:1.92938
83901-88-6 Relevant articles
Assembly of α-(Hetero)aryl Nitriles via Copper-Catalyzed Coupling Reactions with (Hetero)aryl Chlorides and Bromides
Chen, Ying,Xu, Lanting,Jiang, Yongwen,Ma, Dawei
supporting information, p. 7082 - 7086 (2021/02/26)
α-(Hetero)aryl nitriles are important st...
Overcoming inaccessibility of fluorinated imines-synthesis of functionalized amines from readily available fluoroacetamides
Czerwiński, Pawe? J.,Furman, Bart?omiej
supporting information, p. 9436 - 9439 (2019/08/15)
Although imines are convenient substrate...
Synthesis of α-Aryl nitriles through palladium-catalyzed decarboxylative coupling of cyanoacetate salts with aryl halides and triflates
Shang, Rui,Ji, Dong-Sheng,Chu, Ling,Fu, Yao,Liu, Lei
supporting information; experimental part, p. 4470 - 4474 (2011/06/24)
Worth its salt: The palladium-catalyzed ...
Palladium-catalyzed cyanomethylation of aryl halides through domino Suzuki coupling-isoxazole fragmentation
Velcicky, Juraj,Soicke, Arne,Steiner, Roland,Schmalz, Hans-Guenther
supporting information; experimental part, p. 6948 - 6951 (2011/06/19)
A one-pot protocol for the cyanomethylat...
83901-88-6 Process route
-
- 175135-39-4
4-(cyanomethyl)phenyl 4-methylbenzenesulfonate
-
- 201230-82-2
carbon monoxide
-
- 83901-88-6
4-cyanomethylbenzoic acid ethyl ester
Conditions
| Conditions |
Yield |
|
With Josiphos Et2P-Fc-PtBu2 ligand; sodium acetate; palladium diacetate; at 130 - 135 ℃; for 20h; under 2068.59 Torr;
|
93% |
-
- 18293-53-3
2-trimethylsilylacetonitrile
-
- 5798-75-4
Ethyl 4-bromobenzoate
-
- 83901-88-6
4-cyanomethylbenzoic acid ethyl ester
Conditions
| Conditions |
Yield |
|
With tris(dibenzylideneacetone)dipalladium (0); zinc(II) fluoride; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In N,N-dimethyl-formamide; at 90 ℃; for 8h;
|
84% |
83901-88-6 Upstream products
-
26496-94-6
Ethyl 4-(bromomethyl)benzoate
-
18293-53-3
2-trimethylsilylacetonitrile
-
5798-75-4
Ethyl 4-bromobenzoate
-
175135-39-4
4-(cyanomethyl)phenyl 4-methylbenzenesulfonate
83901-88-6 Downstream products
-
99985-38-3
4-cyanomethyl-3-nitro-benzoic acid ethyl ester
-
50820-64-9
indole 6-carboxylic acid ethyl ester
-
50685-26-2
4-(cyanomethyl)benzoic acid
-
1126479-81-9
methyl 4-(1-cyano-3-phenylpropyl)benzoate
